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A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
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The prograde evolution of minerals in metapelites of a Barrovian sequence from the tri-state area (Massachusetts, Connecticut, New York) of the Taconic Range involves assemblages with garnet (Ga), chlorite (Ch), chloritoid (Ct), biotite (Bi) and staurolite (St). Detailed petrologic observations, mineral compositions and chemical zoning in garnet show: (1) garnet high in Mn and Fe but low in Mg is stable with chlorite at grades below those where chloritoid+biotite is found; (2) early formed garnet reacted partially to form Ct+Bi at intermediate grades; (3) at higher grades garnet (with low Mn)+chlorite is again produced, at the expense of chloritoid+biotite, suggesting a reversal in the continuous reaction involving the phases Ga, Ch, Ct and Bi. Thermodynamic modeling of the assemblage Ga+Ch+Ct+Bi±St in the MnKFMASH system reveals: (1) in the MnKFASH system the prograde reaction is Ga+Ch=Ct+Bi whereas in the KFMASH system the prograde reaction is the opposite: Ct+Bi=Ga+Ch; (2) the Ga–Ch–Ct–Bi–St invariant point in the KFMASH system occurs twice, at approximately 6.5 kbar, 545° C and 14.8 kbar, 580° C (although one of them may be metastable in a complex phase system); the appearance of the petrogenetic grid is markedly different from that of Albee, but similar to that of Spear and Cheney; (3) as a consequence, in the KFMASH system, chloritoid+biotite are stable over a wide range of P-T conditions whereas garnet+chlorite assemblages are restricted to a narrow band of P-T conditions; (4) MnO increases the stability field of Ga+Ch relative to both Ct+Bi at low temperatures, and St+Bi at high temperatures; (5) in natural samples the occurrence of Ct+Bi is controlled more by bulk Mg–Fe(-Mn) composition than P-T conditions. Specifically, Ct+Bi is restricted to bulk compositions with Fe/(Mg+Fe+Mn)>0.6. Rocks with Fe/(Mg+Fe+Mn)<0.5 are likely to display only chlorite+biotite at low grade. These observations are consistent with Wang and Spear and Spear and Cheney.  相似文献   
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A molecular dynamics simulation of quartz at different temperatures both in the a and in the phase has been conducted. The - phase transition could be observed. A phonon analysis of the -phase confirms and rounds out in a quantitative way the origin of the incommensurate (ic) modulated phase. In particular it traces the optic soft mode at becoming (to a good approximation) a so-called rigid unit mode (RUM) at q0, and elucidates its coupling to the transverse acoustic mode which precipitates the incommensurate transition. This success underpins and illuminates the concept of RUMs and their role in structural phase transitions.  相似文献   
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Two-dimensional power spectra of solar five-minute oscillations display prominent ridge structures in (k, ω) space, where k is the horizontal wavenumber and ω is the temporal frequency. The positions of these ridges in k and ω can be used to probe temperature and velocity structures in the subphotosphere. We have been carrying out a continuing program of observations of five-minute oscillations with the diode array instrument on the vacuum tower telescope at Sacramento Peak Observatory (SPO). We have sought to establish whether power spectra taken on separate days show shifts in ridge locations; these may arise from different velocity and temperature patterns having been brought into our sampling region by solar rotation. Power spectra have been obtained for six days of observations of Doppler velocities using the Mgi λ5173 and Fei λ5434 spectral lines. Each data set covers 8 to 11 hr in time and samples a region 256″ × 1024″ in spatial extent, with a spatial resolution of 2″ and temporal sampling of 65 s. We have detected shifts in ridge locations between certain data sets which are statistically significant. The character of these displacements when analyzed in terms of eastward and westward propagating waves implies that changes have occurred in both temperature and horizontal velocity fields underlying our observing window. We estimate the magnitude of the velocity changes to be on the order of 100 m s-1; we may be detecting the effects of large-scale convection akin to giant cells.  相似文献   
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Carbon biogeochemistry of the Betsiboka estuary (north-western Madagascar)   总被引:1,自引:0,他引:1  
Madagascar’s largest estuary (Betsiboka) was sampled along the salinity gradient during the dry season to document the distribution and sources of particulate and dissolved organic carbon (POC, DOC) as well as dissolved inorganic carbon (DIC). The Betsiboka was characterized by a relatively high suspended matter load, and in line with this, low DOC/POC ratios (0.4–2.5). The partial pressure of CO2 (pCO2) was generally above atmospheric equilibrium (270–1530 ppm), but relatively low in comparison to other tropical and subtropical estuaries, resulting in low average CO2 emission to the atmosphere (9.1 ± 14.2 mmol m−2 d−1). Despite the fact that C4 vegetation is reported to cover >80% of the catchment area, stable isotope data on DOC and POC suggest that C4 derived material comprises only 30% of both pools in the freshwater zone, increasing to 60–70% and 50–60%, respectively, in the oligohaline zone due to additional lateral inputs. Sediments from intertidal mangroves in the estuary showed low organic carbon concentrations (<1%) and δ13C values (average −19.8‰) consistent with important inputs of riverine imported C4 material. This contribution was reflected in δ13C signatures of bacterial phospholipid derived fatty acids (i + a15:0), suggesting the potential importance of terrestrial organic matter sources for mineralization and secondary production in coastal ecosystems.  相似文献   
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The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ34S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ34S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ34S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ34Spyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe3+ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H2O, not O2. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.  相似文献   
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